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Palladium (II) Complexes of Acetylacetone Dioxime
Author(s) -
BenBassat A. H. I.,
Kaszirer F.
Publication year - 1972
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.197200068
Subject(s) - chemistry , acetylacetone , palladium , titration , inorganic chemistry , elemental analysis , nuclear chemistry , organic chemistry , catalysis
The formation of a sequence of insoluble Pd(II) compounds was demonstrated by heterometric titration. The species Pd 4 AADO (AADO = acetylacetone dioxime), Pd 2 AADO and PdAADO were detected and a further compound, Pd(AADO) 2 was synthesized. The elemental analysis of Pd 2 AADO and Pd(AADOH), is reported. The visible spectrum of Pd/AADO mixtures in solution (at pH = 11) is reported and assigned. IR spectra of Pd 2 AADO, Pd(AADO) 2 and AADO are recorded and compared, and the structure of the compounds is deduced.