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On Some Single‐Crystal Diffraction Experiments in a Search for Direct Structural Evidence for Solid‐State Reactions
Author(s) -
Osaki Kenji,
Schmidt G. M. J.
Publication year - 1972
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.197200024
Subject(s) - chemistry , solid state , cinnamic acid , diffraction , distortion (music) , crystallography , single crystal , crystal structure , crystal (programming language) , x ray crystallography , organic chemistry , optics , amplifier , physics , cmos , electronic engineering , engineering , programming language , computer science
Solid‐state reactions were studied by X‐ray diffraction using single crystals of 1′‐bromo‐ cis ‐cinnamic acid, α ‐ trans ‐cinnamic acid and trans ‐cinnamide. Only in the last case was direct structural evidence for the solid‐state reaction obtained through the deformation of the X‐ray pattern of the original crystal, which indicates considerable distortion accumulated in the crystalline matrix of the reacting species.