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Inductive Effects on Molecular Ionization Potentials. V. Hydrogen Sulfide and Aliphatic Thioethers
Author(s) -
Levitt L.S.,
Levitt Barbara W.
Publication year - 1971
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.197100099
Subject(s) - chemistry , substituent , inductive effect , ionization , alkyl , polar , hydrogen atom , ionization energy , hydrogen sulfide , chemical polarity , sulfide , computational chemistry , medicinal chemistry , photochemistry , organic chemistry , molecule , ion , sulfur , physics , astronomy
The ionization energies of thioethers, R 2 S, have been correlated with the polar substituent constants and the inductive substituent constants. Good correlations are obtained which indicate that the effect of alkyl substituents on the S‐atom is primarily an inductive one.