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Preparation and Properties of Tricyclopentadienyl Cerium (IV) Chloride and Bisindenyl Cerium (IV) Dichloride
Author(s) -
Kalsotra B.L.,
Multani R.K.,
Jain B.D.
Publication year - 1971
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.197100077
Subject(s) - cerium , chemistry , tetrahydrofuran , sodium , inorganic chemistry , chloride , nuclear chemistry , yield (engineering) , organic chemistry , metallurgy , materials science , solvent
The reactions of dipyridinium cerium (IV) hexachloride with tetracyclopentadienyl cerium or sodium cyclopentadienide and tetraindenyl cerium or sodium indenide in tetrahydrofuran yield tricyclopentadienyl cerium (IV) chloride and bisindenyl cerium (IV) dichloride. Infrared spectra, thermal stabilities and other characteristics of the compounds have been studied.