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Inductive Effects on Molecular Ionization Potentials. III. Primary, Secondary and Tertiary Aliphatic Amines
Author(s) -
Levitt Barbara W.,
Levitt L. S.
Publication year - 1971
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.197100011
Subject(s) - chemistry , substituent , primary (astronomy) , ionization , inductive effect , ammonia , tertiary amine , polar , computational chemistry , ionization energy , organic chemistry , ion , physics , astronomy
It is demonstrated that the ionization potentials of primary, secondary, and tertiary aliphatic amines correlate very well with the inductive and polar substituent constants, the only seriously deviating value being that for ammonia, itself. The correlation equation is found to be E I = 9.62 + 13.8 Σσ I .
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