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Electrocatalytic Oxidation of Amines on Platinum Electrodes. Part III. Oxidation Of Ethylenediamine Via Higher Oxidation States of Nickel
Author(s) -
Fried I.,
Meyerstein D.
Publication year - 1970
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.197000111
Subject(s) - chemistry , ethylenediamine , nickel , platinum , aqueous solution , inorganic chemistry , electrochemistry , electrode , catalysis , organic chemistry
The voltammetric behaviour of aqueous nickel ethylenediamine solutions has been studied. Electrocatalytic oxidation waves were obtained which are attributed to the formation of trivalent and possibly also tetravalent nickel ethylenediamine complexes as intermediates. The mechanism of the electrocatalytic process is discussed.