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Reactions of Fluorine Nitrate with Lewis Acids
Author(s) -
Shamir J.,
Yellin D.
Publication year - 1969
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.196900054
Subject(s) - chemistry , raman spectroscopy , lewis acids and bases , fluorine , oxygen , nitrate , inorganic chemistry , oxygen atom , organic chemistry , molecule , catalysis , physics , optics
FNO 3 reacts with BF 3 , PF 5 , AsF 5 and SbF 5 , to form white solids identified as nitryl salts of general formula NO 2 + X − . Molecular oxygen is released during the reaction. The structure of these solids and identification of the oxygen were supported by the Raman spectra, gas pressure measurements and molecular weight.