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The Solvolysis and Rearrangement of Benzyl Arenesulfinates
Author(s) -
Braverman S.,
Steiner S.
Publication year - 1967
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.196700047
Subject(s) - chemistry , solvolysis , fission , oxygen , mechanism (biology) , sulfur , photochemistry , ionization , computational chemistry , medicinal chemistry , organic chemistry , hydrolysis , ion , philosophy , physics , epistemology , quantum mechanics , neutron
A kinetic study of the solvolysis and rearrangement of p ‐methoxybenzyl arenesulfinates was made. In contrast to the sulfur‐oxygen bond fission mechanism which prevails for benzyl arenesulfinates, a carbon‐oxygen bond fission by an ionization mechanism was found for the corresponding p ‐methoxybenzyl esters.