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Kinetics of the Nucleophilic Substitution Reaction Between 2,4‐Dinitrochlorobenzene and Azide Ions
Author(s) -
Patai S.,
Gotshal Y.
Publication year - 1965
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.196500053
Subject(s) - chemistry , azide , nucleophilic substitution , nucleophile , ion , kinetics , substitution reaction , medicinal chemistry , photochemistry , organic chemistry , catalysis , physics , quantum mechanics
The reaction between azide ions and 2,4‐dinitrochlorobenzene was found to be of first order in each of the reactants. The reaction is slower in more polar media, and is completely inhibited by acid. The place of azide ions in the nucleophilicity order of aromatic substituting agents is assigned.