Premium
The Iodination of Borazines
Author(s) -
Muszkat K.A.,
Kirson B.
Publication year - 1963
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.196300031
Subject(s) - chemistry , halogenation , iodine , borazine , iodine compounds , medicinal chemistry , organic chemistry , boron nitride
N‐Trimethyl‐ and N‐triphenylborazines were iodinated by elemental iodine giving B‐mono‐, B‐di‐ and B‐triiodo‐N‐trimethylborazines and B‐mono‐ and B‐di‐iodo‐N‐triphenylborazines. Borazine itself, however, yields on iodination a non‐volatile product whose structure is discussed. A possible mechanism for the iodination reaction is considered. The charge transfer complex of N‐triphenylborazine and iodine is described.