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Organic Fluorine Compounds: Part XXX : Experiments in the Fluoroglutaric Acid Series
Author(s) -
Bergmann E. D.,
Cohen S.,
Shani A.
Publication year - 1963
Publication title -
israel journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 54
eISSN - 1869-5868
pISSN - 0021-2148
DOI - 10.1002/ijch.196300017
Subject(s) - chemistry , acrylonitrile , decarboxylation , methyl acrylate , hydrolysis , organic chemistry , acrylate , fluorine , polymer , catalysis , monomer , copolymer
The products (e.g. I, II) obtained by Michael reaction between acrylonitrile or methyl acrylate and diethyl fluoromalonate or — preferably — fluoromalondiamide, gave upon hydrolysis and partial decarboxylation, 2‐fluoroglutaric acid (III). The reactions of this acid as well as some other attempts at new routes leading to γ‐fluoroglutamic acid (XV) are described.