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Uranium and thorium isotopes in the rivers of the Amazonian basin: hydrology and weathering processes
Author(s) -
Marques Aguinaldo N.,
AlGharib Iyad,
Bernat Michel,
Fernex François
Publication year - 2003
Publication title -
hydrological processes
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.222
H-Index - 161
eISSN - 1099-1085
pISSN - 0885-6087
DOI - 10.1002/hyp.1112
Subject(s) - tributary , hydrology (agriculture) , blackwater , drainage basin , geology , uranium , particulates , weathering , amazonian , amazon rainforest , environmental science , environmental chemistry , geochemistry , chemistry , environmental engineering , geography , metallurgy , cartography , geotechnical engineering , organic chemistry , materials science , ecology , biology
Two expeditions (October 1989 and May 1992) were carried out to two points of the main Amazon River channel and four tributaries. The Solimões and Madeira rivers, taking their origin in the Andes, are whitewater rivers. The Negro River is a typical acid, blackwater river. The Trombetas River flows through bauxite‐rich areas, and is characterized by low concentrations of dissolved humic substances. The 238 U, 234 U, 232 Th and 230 Th activities were recorded from dissolved, suspended particulate phases and river bank sediments. The latter were analysed for their 226 Ra, 228 Ra and 210 Pb contents, and also subjected to leaching with 0·2 M hydroxylamine–hydrochloride solution to determine the concentrations of radionuclides bound to amorphous Fe hydroxides and Mn oxides and hydroxides. The dissolved U average concentration in the Amazon system is ten times lower than the mean world river concentration. The uranium concentration observed at Óbidos in the lower Amazon (0·095 µg L −1 ), where the U content in the river bank sediments and suspended matter is lowest, suggests U release from the solid phase during river transport. About 485 t of U are transported annually to the Amazon delta area in dissolved form, and 1943 t bound to suspended particulate matter. Total U and Th concentrations in the river bank sediments ranged from 1·59 to 7·14 µg g −1 and from 6·74 to 32 µg g −1 , respectively. The highest concentrations were observed in the Trombetas River. The proportion extracted by means of the hydroxylamine solution (HL) was relatively high for U in the Trombetas river bank sediment (31%) and for Th in the Solimões sediment (30%). According to the alpha recoil effects, the 234 U/ 238 U activity ratios of the Andean river waters and downstream Amazon water (Óbidos) were >1, but were <1 in the Negro River (at Manaus). The activity ratios of dissolved U correlate with pH and also with the U activity ratios in the river bank sediment hydroxylamine extracts. As expected, the 234 U/ 238 U activity ratios in river bank sediments were <1 in the Andean rivers and in the downstream Amazon, but they were >1 in the Trombetas and Negro rivers. Such ratios probably result from the binding of dissolved uranium to solid sediment. The 228 Th/ 232 Th ratios of river bank sediments were close to unity (except for the Negro River, where it is lower), suggesting no significant Th exchanges between the river water and the sediment. The 226 Ra/ 232 Th activity ratios were <1, and the 226 Ra/ 228 Ra activity ratios generally were significantly higher than the activity ratios of their respective parents. This perhaps is the result of easier leaching of the 226 Ra parent, 230 Th, from solid material (owing to the alpha recoil effect) than of the 228 Ra parent. Uranium and thorium isotopes were used as tools to evaluate the chemical weathering rate of rocks in the Amazon system, which was estimated to be 2·7 cm 1000 year −1 s −1 . Copyright © 2002 John Wiley & Sons, Ltd.