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Spectrally selective coating of nanoparticles (Co 3 O 4 :Cr 2 O 3 ) incorporated in carbon to captivate solar energy
Author(s) -
Abed Rasheed N.,
Abdallh Mustafa,
Adnan Rashad Alaa,
AlMohammedawi Haidar Ch.,
Yousif Emad
Publication year - 2020
Publication title -
heat transfer
Language(s) - English
Resource type - Journals
eISSN - 2688-4542
pISSN - 2688-4534
DOI - 10.1002/htj.21668
Subject(s) - materials science , nanocomposite , molar absorptivity , analytical chemistry (journal) , nanoparticle , carbon fibers , dopant , doping , coating , band gap , nanotechnology , composite material , optoelectronics , optics , composite number , chemistry , physics , chromatography
Abstract Innovatory nanocomposite comprising nanomaterials Co 3 O 4 :Cr 2 O 3 and carbon (fuel ash) was designed to absorb solar energy. Different concentration ratios of Co 3 O 4 and Cr 2 O 3 nanoparticles were utilized as a dopant for fuel thin films synthesis via spin and casting methods on glass and aluminum substrates. The optical properties of the modified films demonstrated in the range of 250 to 1300 nm. The data were interpreted in terms of a phonon‐assisted theory. Energy gap ( E g ) of doped C was calculated with different concentration ratios of Co 3 O 4 :Cr 2 O 3 (0.5:2.5, 1:2, 1.5:1.5, 2:1, 2.5:0.5) wt%, and fixed concentration of C in 7wt%. The results showed E g of the doped samples in the range of 2.9 to 3.9 eV. In addition, the intensity of the solar radiation was measured. The absorptivity was in the range of 88 to 93.6%. The above results are comparable to those of semiconductors and have high absorptivity values when the nanocomposite was utilized on a flat plate collector as a coating to trap and absorb solar energy.