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Reaktionen von niederwertigen Di‐cyclopentadienyl‐titan‐Verbindungen mit Sauerstoff und Stickstoffmonoxid
Author(s) -
Salzmann J.J
Publication year - 1968
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.660510427
Subject(s) - chemistry , cyclopentadienyl complex , titanium , oxygen , titanio , infrared spectroscopy , infrared , inorganic chemistry , polymer chemistry , organic chemistry , catalysis , transition metal , physics , optics
The reactions of di‐cyclpentadienyl‐titanium and di‐cyclopentadienyl‐di‐carbonyl‐titanium with oxygen lead to polymeric di‐cyclopentadienyl‐peroxo‐titanium. The reaction of di‐cyclopentadienyl‐titanium with nitrogen oxide gives a polymeric hyponitrit‐titanium compound. Both derivatives have been investigated by infrared spectra and gaschromatography.