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Photoredox Reaction of Naphthoquinone C ‐Glycoside Revisited: Insight into Stereochemical Aspect
Author(s) -
Ando Yoshio,
Matsumoto Takashi,
Suzuki Keisuke
Publication year - 2021
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.202100008
Subject(s) - chemistry , naphthoquinone , glycosyl , glycoside , stereochemistry , computational chemistry , organic chemistry
Insights into the naphthoquinone photoredox reactions have been gained from the reactions of a C ‐glycosyl naphthoquinone. The retentiveness comes from the balance of the lifetime of intermediary zwitterionic species relative to the conformational change to bring about the stereo‐mutating C−C bond rotation.
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