Transition Metal‐Free Alkyne‐Aldehyde Reductive C−C Coupling trough Cascade Borylation/Olefin Isomerization | Zendy

Khan Imran | Zendy; Luo Zhibin | Zendy; Xu Yin | Zendy; Xie Jimin | Zendy; Zhu Weihua | Zendy; Liu Bin | Zendy

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Transition Metal‐Free Alkyne‐Aldehyde Reductive C−C Coupling trough Cascade Borylation/Olefin Isomerization

Author(s) -

Khan Imran,

Luo Zhibin,

Xu Yin,

Xie Jimin,

Zhu Weihua,

Liu Bin

Publication year - 2020

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.202000028

Subject(s) - chemistry , alkyne , isomerization , aldehyde , cascade , propargyl , borylation , olefin fiber , transition metal , organic chemistry , combinatorial chemistry , photochemistry , catalysis , alkyl , chromatography , aryl

A direct approach to γ ‐keto esters through cascade alkyne‐aldehyde reductive C−C coupling of propargyl esters and aromatic aldehydes under transition‐metal‐free (TM‐free) fashion was developed. Compared with multistep processes, this procedure provides a fast path using commercially available materials and could be handled conveniently to produce various γ ‐keto esters in moderate yields.

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