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New Calix[4]arene‐Cored Peripherally Functionalized Dendrimers: Synthesis and Conformational Characteristics
Author(s) -
Paraskevopoulos Georgios,
Alivertis Dimitrios,
Theodorou Vassiliki,
Skobridis Konstantinos
Publication year - 2015
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.201400304
Subject(s) - dendrimer , chemistry , calixarene , ether , macromolecule , polymer chemistry , stereochemistry , molecule , organic chemistry , biochemistry
New calixarene‐based dendrimers, containing calix[4]arene as the core and different generations of Fréchet ‐type poly(benzyl ether) dendrons as building blocks, which possess either Br‐atoms or COO t Bu groups at their surface were synthesized and presented herein for the first time. The new calix[4]arene‐cored dendritic macromolecules were fully characterized and found to prefer strictly the cone conformation.