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Palladium‐Catalyzed Arylation of Olefins by Triarylphosphines via CP Bond Cleavage
Author(s) -
Lu Dapeng,
Xu Yu,
Liu Wenjing,
Guo Lijuan,
Sun Xingxia
Publication year - 2015
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.201400152
Subject(s) - chemistry , palladium , catalysis , bond cleavage , cleavage (geology) , medicinal chemistry , stereochemistry , organic chemistry , geotechnical engineering , fracture (geology) , engineering
CH Arylation of olefins by triarylphosphines via CP bond cleavage has been achieved with either Pd 0 or Pd II catalysts. A variety of olefins and triarylphosphines are tolerated, and we inferred that both Pd 0 and Pd II could function directly without pre‐oxidation or pre‐reduction.