PN Bond Cleavage during the Insertion of Carbon Fragments into P III N Bonds in Bis(diphenylphosphino) Amines | Zendy

Biricik Nermin | Zendy; Kayan Cezmi | Zendy; Gümgüm Bahattin | Zendy

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PN Bond Cleavage during the Insertion of Carbon Fragments into P III N Bonds in Bis(diphenylphosphino) Amines

Author(s) -

Biricik Nermin,

Kayan Cezmi,

Gümgüm Bahattin

Publication year - 2014

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.201400074

Subject(s) - chemistry , toluene , cleavage (geology) , yield (engineering) , amine gas treating , bond cleavage , medicinal chemistry , carbon fibers , single bond , carbon–carbon bond , organic chemistry , catalysis , group (periodic table) , materials science , geotechnical engineering , fracture (geology) , composite number , engineering , metallurgy , composite material

The reaction of tertiary amine functionalized phosphines with aromatic and aliphatic aldehydes gives insertion of carbon fragments into the P III N bonds or P III N bond cleavage. The reaction of bis(diphenylphosphino) amines, 1a – 1c , with two equiv. of aldehydes in toluene afforded the P III N bond inserted products, 2a – 4a, 4b – 6b , and 3c – 5c , in moderate‐to‐good yield. The products were characterized by IR, 1 H‐ and 31 P‐NMR spectroscopy and elemental analysis.

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