Stereoselective Total Synthesis of Botryolide E and Ophiocerin C | Zendy

Yadav Jhillu S. | Zendy; Mallikarjuna Reddy N. | Zendy; Ataur Rahman Md. | Zendy; Mallikarjuna Reddy A. | Zendy; Prasad Attaluri R. | Zendy

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Stereoselective Total Synthesis of Botryolide E and Ophiocerin C

Author(s) -

Yadav Jhillu S.,

Mallikarjuna Reddy N.,

Ataur Rahman Md.,

Mallikarjuna Reddy A.,

Prasad Attaluri R.

Publication year - 2014

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.201300203

Subject(s) - tetrahydropyran , chemistry , prins reaction , stereoselectivity , derivative (finance) , lactone , total synthesis , polyketide , stereochemistry , sequence (biology) , organic chemistry , ring (chemistry) , catalysis , biochemistry , biosynthesis , financial economics , economics , enzyme

A highly stereoselective approach to the total synthesis of the γ ‐lactone derivative botryolide E and tetrahydropyran derivative ophiocerin C via a common polyketide precursor by means of Prins cyclization and MacMillan α ‐aminoxylation sequence is described. The method can conveniently be utilized for the preparation of further related γ ‐lactone and tetrahydropyran derivatives.

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