2‐Amino‐1,2,3,6‐tetrahydro‐6‐oxocyclopenta[ c ]fluorene‐2‐carboxylic Acid (FlAib), a Completely Rigidified, Fluoren‐9‐one‐Based  α ‐Amino Acid | Zendy

Wright Karen | Zendy; Alvarez Antonio Blanco | Zendy; Crisma Marco | Zendy; Toffoletti Antonio | Zendy; Formaggio Fernando | Zendy; Toniolo Claudio | Zendy

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2‐Amino‐1,2,3,6‐tetrahydro‐6‐oxocyclopenta[ c ]fluorene‐2‐carboxylic Acid (FlAib), a Completely Rigidified, Fluoren‐9‐one‐Based α ‐Amino Acid

Author(s) -

Wright Karen,

Alvarez Antonio Blanco,

Crisma Marco,

Toffoletti Antonio,

Formaggio Fernando,

Toniolo Claudio

Publication year - 2012

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.201200490

Subject(s) - chemistry , fluorene , carboxylic acid , glycine , amino acid , stereochemistry , absolute configuration , resolution (logic) , organic chemistry , polymer , biochemistry , artificial intelligence , computer science

The synthesis, optical resolution, determination of absolute configuration and conformational preference, and spectroscopic characteristics of terminally protected (blocked) derivatives and short peptides of 2‐amino‐1,2,3,6‐tetrahydro‐6‐oxocyclopenta[ c ]fluorene‐2‐carboxylic acid (FlAib), a novel, rigid, chiral, cyclized C α , α ‐disubstituted glycine are described.

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