2,3,10,11‐Tetrahydroxytetraphenylene and Its Application in Molecular Recognition | Zendy

Cui JianFang | Zendy; Chen Chao | Zendy; Gao Xiang | Zendy; Cai ZongWei | Zendy; Han JianWei | Zendy; Wong Henry N. C. | Zendy

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2,3,10,11‐Tetrahydroxytetraphenylene and Its Application in Molecular Recognition

Author(s) -

Cui JianFang,

Chen Chao,

Gao Xiang,

Cai ZongWei,

Han JianWei,

Wong Henry N. C.

Publication year - 2012

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.201200485

Subject(s) - chemistry , derivative (finance) , block (permutation group theory) , molecular recognition , paraquat , host (biology) , combinatorial chemistry , stereochemistry , molecule , organic chemistry , combinatorics , ecology , mathematics , financial economics , economics , biology

A rationally designed 2,3,10,11‐tetrahydroxytetraphenylene ( 1 ) has been synthesized. Employing 1 as a building block, a structurally novel tweezer‐like host 2 containing dibenzo‐24‐crown‐8 moieties has been prepared. Host 2 showed excellent molecular‐recognition ability toward paraquat (=1,1′‐dimethyl‐4,4′‐bipyridinium dichloride) derivative 3a to form a 1 : 1 stable complex in solution.

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