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Studies on AlkylNitrogen Bond Formation via Reductive Elimination from Monomeric Palladium Complexes in High Oxidation State
Author(s) -
Iglesias Álvaro,
Muñiz Kilian
Publication year - 2012
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.201200430
Subject(s) - chemistry , palladium , substituent , alkyl , oxidation state , nitrogen , denticity , ligand (biochemistry) , reductive elimination , monomer , medicinal chemistry , catalysis , photochemistry , polymer chemistry , organic chemistry , metal , polymer , biochemistry , receptor
Oxidation of a series of defined palladium(II) complexes bearing a bidentate ligand, and a methyl and an amidato substituent was carried out with the aim to gain a better understanding of the inherent requirements for CN bond‐formation from Pd complexes in high oxidation state. This work clarified the role of the individual nitrogen sources and has important implication for alkylnitrogen bond‐forming reactions catalyzed by Pd.