Stereoselective Total Synthesis of Passifloricin A | Zendy

Reddy Cheruku Ravindra | Zendy; Veeranjaneyulu Boyapati | Zendy; Nagendra Siddavatam | Zendy; Das Biswanath | Zendy

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Stereoselective Total Synthesis of Passifloricin A

Author(s) -

Reddy Cheruku Ravindra,

Veeranjaneyulu Boyapati,

Nagendra Siddavatam,

Das Biswanath

Publication year - 2013

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.201200356

Subject(s) - chemistry , stereoselectivity , total synthesis , olefin metathesis , metathesis , stereochemistry , olefin fiber , antiprotozoal , salt metathesis reaction , carbonate , combinatorial chemistry , organic chemistry , catalysis , biochemistry , polymer , in vitro , polymerization

The stereoselective total synthesis of passifloricin A ( 1 ), a naturally occurring dihydropyranone with leishmanicidal and antiprotozoal activities, has been accomplished starting from protected glyceraldehyde using Maruoka asymmetric allylation, diastereoselective iodo‐carbonate cyclization, and Grubbs ' olefin metathesis reactions as the key steps.

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