A Fused Benzocyclooctene Ring System  via  an Aromatic  Cope  Rearrangement: Thermal Reactions of  trans ‐1‐Aryl‐2‐ethenylcyclobutanecarbonitriles | Zendy

ÁvilaZárraga José Gustavo | Zendy; VázquezSánchez Adrián | Zendy; Maldonado Luis Ángel | Zendy

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A Fused Benzocyclooctene Ring System via an Aromatic Cope Rearrangement: Thermal Reactions of trans ‐1‐Aryl‐2‐ethenylcyclobutanecarbonitriles

Author(s) -

ÁvilaZárraga José Gustavo,

VázquezSánchez Adrián,

Maldonado Luis Ángel

Publication year - 2013

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.201200352

Subject(s) - chemistry , aryl , ring (chemistry) , cope rearrangement , transformation (genetics) , smiles rearrangement , stereochemistry , medicinal chemistry , organic chemistry , biochemistry , alkyl , gene

The results of an aromatic Cope rearrangement of a trans ‐1‐aryl‐2‐ethenylcyclobutanecarbonitrile are reported ( Scheme ). The use of this rearrangement for the construction of the fused benzocyclooctene ring system and a preliminary study of the electronic requirements to favor such a transformation are also described.

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