X‐Ray Structure Study of an Unusual 13,14,15,16‐Tetranorlabdane Derivative Obtained in the Synthesis of (7 α )‐7,8‐Dihydroxy‐14,15‐dinorlabdane‐11,13‐dione | Zendy

Kravtsov Victor C. | Zendy; Gorincioi Elena C. | Zendy; Barba Alic N. | Zendy; Aricu Aculi. | Zendy; Lipkowski Janusz | Zendy; Vlad Pavel F. | Zendy

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X‐Ray Structure Study of an Unusual 13,14,15,16‐Tetranorlabdane Derivative Obtained in the Synthesis of (7 α )‐7,8‐Dihydroxy‐14,15‐dinorlabdane‐11,13‐dione

Author(s) -

Kravtsov Victor C.,

Gorincioi Elena C.,

Barba Alic N.,

Aricu Aculi.,

Lipkowski Janusz,

Vlad Pavel F.

Publication year - 2012

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.201100412

Subject(s) - chemistry , derivative (finance) , crystal structure , x ray , hydrolysis , stereochemistry , crystallography , organic chemistry , physics , quantum mechanics , financial economics , economics

The unconventional (5 S ,7 R ,8 S ,9 R ,10 S )‐configurated (−)‐7‐(acetyloxy)‐12,12‐dichloro‐8‐hydroxy‐13,14,15,16‐tetranorlabdan‐11‐one ( 2 ) was synthesized via the HCl‐promoted hydrolysis of (7 α )‐7,8‐(isopropylidenedioxy)‐14,15‐dinorlabdan‐11,13‐dione ( 5 ). Possible mechanistic pathways of the reaction are considered. Crystal and molecular structures of the isolated compound 2 were determined by single‐crystal X‐ray structure analysis.

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