A Novel 1‐Glycosyl‐1 H ‐triazole‐Based  P , N  Ligand for Rhodium‐Catalyzed Asymmetric Hydrosilylation of Ketones | Zendy

Shen Chao | Zendy; Zhang PengFei | Zendy; Chen XinZhi | Zendy

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A Novel 1‐Glycosyl‐1 H ‐triazole‐Based P , N Ligand for Rhodium‐Catalyzed Asymmetric Hydrosilylation of Ketones

Author(s) -

Shen Chao,

Zhang PengFei,

Chen XinZhi

Publication year - 2010

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.201000093

Subject(s) - hydrosilylation , chemistry , acetophenone , enantioselective synthesis , rhodium , glycosyl , ligand (biochemistry) , catalysis , triazole , stereochemistry , medicinal chemistry , organic chemistry , combinatorial chemistry , biochemistry , receptor

A novel class of chiral glycosyl‐triazole‐based P , N ligands were synthesized by ‘click chemistry’ and were applied to the Rh‐catalyzed asymmetric hydrosilylation of a range of substituted acetophenones. Enantioselective hydrosilylation of acetophenone gave ( S )‐1‐phenylethanol in moderate enantioselectivity (72% ee) and in good conversion (93%).

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