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Enantioselective Synthesis of Herbarumin III by Using a Chelation‐Controlled Reduction
Author(s) -
Sabitha Gowravaram,
Srinivas Chitti,
Maruthi Chittapragada,
Yadav Jhillu Singh
Publication year - 2010
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.200900427
Subject(s) - chemistry , enantioselective synthesis , chelation , reduction (mathematics) , aldehyde , combinatorial chemistry , total synthesis , stereochemistry , organic chemistry , catalysis , geometry , mathematics
The total synthesis of herbarumin III ( 1 ) was achieved via an alkynide ion addition onto a chiral aldehyde and LiAlH 4 /LiI reduction as key steps ( Scheme 2 ).
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