Na 6 [Ti 5 O 12 (OH) 2 ]: A New Titanate Containing  $\rm{{_{\infty }^{1}}}$ [Ti 5 O 12 (OH) 2 ] 6−  Ribbons | Zendy

Wörle Michael | Zendy; Lorenzen Volker | Zendy; Nesper Reinhard | Zendy

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Na 6 [Ti 5 O 12 (OH) 2 ]: A New Titanate Containing $\rm{{_{\infty }^{1}}}$ [Ti 5 O 12 (OH) 2 ] 6− Ribbons

Author(s) -

Wörle Michael,

Lorenzen Volker,

Nesper Reinhard

Publication year - 2009

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.200900255

Subject(s) - chemistry , orthorhombic crystal system , autoclave , crystallography , hydrothermal circulation , crystal structure , titanate , lattice constant , hydrothermal reaction , analytical chemistry (journal) , inorganic chemistry , physics , diffraction , ceramic , organic chemistry , optics , chromatography , seismology , geology

Na 6 [Ti 5 O 12 (OH) 2 ] is the first structurally characterized sodium oxohydroxotitanate. The compound can be prepared via hydrothermal treatment of TiO 2 (Anatas) in NaOH (10 n ) for 96 h at 250° in an autoclave. The crystal structure of Na 6 [Ti 5 O 12 (OH) 2 ] consists of infinite ribbons $\rm{{_{\infty }^{1}}}$ [Ti 5 O 12 (OH) 2 ] 6− . The orthorhombic arrangement has Pbcn (No. 60) symmetry with the lattice constants a =18.668(4) Å, b =6.5333(13) Å, and c =9.829(2) Å.

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