Total Synthesis of (+)‐Cryptocaryalactone and of a Diastereoisomer of (+)‐Strictifolione  via  Ring‐Closing Metathesis (RCM) and Olefin Cross‐Metathesis (CM) | Zendy

Sabitha Gowravaram | Zendy; Vangala Bhaskar | Zendy; Reddy S. Siva Sankara | Zendy; Yadav Jhillu S. | Zendy

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Total Synthesis of (+)‐Cryptocaryalactone and of a Diastereoisomer of (+)‐Strictifolione via Ring‐Closing Metathesis (RCM) and Olefin Cross‐Metathesis (CM)

Author(s) -

Sabitha Gowravaram,

Vangala Bhaskar,

Reddy S. Siva Sankara,

Yadav Jhillu S.

Publication year - 2010

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.200900170

Subject(s) - chemistry , diastereomer , metathesis , ring closing metathesis , olefin metathesis , malic acid , acyclic diene metathesis , stereochemistry , salt metathesis reaction , ring (chemistry) , organic chemistry , polymerization , citric acid , polymer

Ring‐closing metathesis (RCM) and olefin cross‐metathesis (CM) reactions were used as the key steps for the synthesis of (+)‐cryptocaryalactone ( 1 ) and the first synthesis of the diastereoisomer 3 of (+)‐strictifolione, starting from the commercially available L ‐malic acid (=(2 S )‐2‐hydroxybutanedioic acid).

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