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Trichocarpinine, a Novel Hetidine–Hetisine Type Bisditerpenoid Alkaloid from Aconitum tanguticum var. trichocarpum
Author(s) -
Lin Ling,
Chen DongLin,
Liu XiaoYu,
Chen QiaoHong,
Wang FengPeng
Publication year - 2010
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.200900128
Subject(s) - chemistry , alkaloid , aconitum , stereochemistry
Trichocarpinine ( 1 ), the first hetidine–hetisine type bisditerpenoid alkaloid, was isolated from the whole herbs of Aconitum tanguticum var. trichocarpum. Its structure was determined by a combination of spectroscopic techniques, including HR‐ESI‐MS and 1D‐ and 2D‐NMR experiments. Its plausible biogenetic pathway was proposed as well ( Scheme ).