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Deracemization of a Macrocyclic 1,1′‐Biisoquinoline
Author(s) -
Dyker Gerald,
Stirner Wolfgang,
Henkel Gerald,
Schreiner Peter R.
Publication year - 2008
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.200890095
Subject(s) - chemistry , stereochemistry , combinatorial chemistry
The macrocyclic biisoquinoline 14 was synthesized in just four preparative steps starting from the simple biscarboxaldehyde 8 . The interaction with camphorsulfonic acid induces an acid‐catalyzed partial deracemization.