New Cembranoids from the Hainan Soft Coral  Sarcophyton glaucum | Zendy

Yao LiGong | Zendy; Liu HaiLi | Zendy; Guo YueWei | Zendy; Mollo Ernesto | Zendy

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New Cembranoids from the Hainan Soft Coral Sarcophyton glaucum

Author(s) -

Yao LiGong,

Liu HaiLi,

Guo YueWei,

Mollo Ernesto

Publication year - 2009

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.200800417

Subject(s) - chemistry , coral , absolute configuration , stereochemistry , enantiomer , oceanography , geology

From the soft bodied coral Sarcophyton glaucum collected from the South China Sea two new cembranoids, (7 R ,8 S )‐dihydroxydeepoxy‐ ent ‐sarcophine ( 1 ) and secosarcophinolide ( 2 ), together with one known related compound, ent ‐sarcophine ( 3 ), were isolated. The structures of the new compounds were determined by extensive analysis of their spectroscopic data and chemical correlation. The absolute configuration of 1 was determined by chemical correlation with 3 and by comparison of its optical rotation value with that of its corresponding enantiomer, (7 S ,8 R )‐dihydroxydeepoxysarcophine ( 5 ).

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