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Selectivity Enhancement for the Jacobsen–Katsuki Epoxidation in Fluorinated Solvents
Author(s) -
Havare Nizam,
Plattner Dietmar A.
Publication year - 2009
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.200800381
Subject(s) - chemistry , selectivity , ligand (biochemistry) , oxide , medicinal chemistry , combinatorial chemistry , organic chemistry , receptor , catalysis , biochemistry
In 1,1,1,2,3,4,4,5,5,5‐Decafluoropentane using 2‐phenylpyridine N‐ oxide as donor ligand, the enantioselectivity of the Jacobsen–Katsuki epoxidation is improved up to 10% ee as compared to established protocols.
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