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Synthesis of Phenyl‐Substituted Conduritol B and Its Mechanism of Formation
Author(s) -
Cantekin Seda,
Çalışkan Raşit,
Şahin Ertan,
Balci Metin
Publication year - 2007
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.200790231
Subject(s) - chemistry , sequence (biology) , mechanism (biology) , stereochemistry , benzoquinone , organic chemistry , biochemistry , philosophy , epistemology
The phenyl‐substituted conduritol B 8 was prepared in racemic form in a five‐step sequence starting from 2‐phenyl‐1,4‐benzoquinone ( 10 ) ( Scheme 1 ). The reaction mechanism of the key step 12b → 13 is discussed ( Scheme 2 ).