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β ‐Cyclodextrin‐Supported, Completely Regioselective Ring Opening of Thiiranes with Thiophenol in Water
Author(s) -
Reddy Majjigapu Somi,
Surendra Karavadi,
Krishnaveni Neelam Srilakshmi,
Narender Mendu,
Rao Kakulapati Rama
Publication year - 2007
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.200790039
Subject(s) - regioselectivity , chemistry , thiophenol , thiolysis , cyclodextrin , ring (chemistry) , thiirane , combinatorial chemistry , organic chemistry , catalysis , polyphenol , proanthocyanidin , antioxidant
Thiolysis of thiiranes I with thiophenols II is performed efficiently in the presence of β ‐cyclodextrin in water with high regioselectivity ( Scheme, Table ).