Premium
Efficient Regio‐ and Stereoselective Conversions of Oxiranes and Aziridines into β ‐(Nitrooxy)‐Substituted Alcohols and Amines by Using Bismuth Nitrate
Author(s) -
Das Biswanath,
Krishnaiah Maddeboina,
Venkateswarlu Katta,
Reddy Vtukuri Saidi
Publication year - 2007
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.200790002
Subject(s) - chemistry , stereoselectivity , ring (chemistry) , bismuth , organic chemistry , medicinal chemistry , catalysis
Oxiranes and aziridines efficiently undergo ring opening with bismuth nitrate at room temperature to furnish the corresponding β ‐(nitrooxy)‐substituted alcohols and amines respectively. The conversions are highly regio‐ and stereoselective and afford the nitrooxy‐compounds in excellent yields within a short period of time.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom