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Homolytic Substitution at the Sulfur Atom as a Tool for Organic Synthesis
Author(s) -
Crich David
Publication year - 2006
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.200690204
Subject(s) - homolysis , chemistry , radical , sulfur , intramolecular force , substitution (logic) , alkyl , aryl , halide , organic synthesis , radical substitution , atom (system on chip) , substitution reaction , organic chemistry , medicinal chemistry , photochemistry , catalysis , computer science , embedded system , programming language
The use of intramolecular homolytic substitution at the sulfur atom by aryl and vinyl radicals, as an alternative to the use of alkyl halides, and chalcogenides as radical precursors in organic synthesis is reviewed.