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A Novel Three‐Dimensional Coordination Polymer Involving PbPb Interactions and Three Different Hemidirected Lead(II) Coordination Spheres: X‐Ray Crystal Structure of Tris(1,10‐phenanthroline‐ κN 1 , κN 10 )bis[{ μ 3 ‐[5‐(sulfo‐ κO )benzene‐1,3‐dicarboxylate(3−)‐ κO 1 , κO 1′ : κO 2 , κO 2′ : κO 2 ]}trilead ( PbPb ) Trihydrate ([Pb 3 (phen) 3 (H 2 O) 2 (sip) 2 ] n ⋅3 H 2 O)
Author(s) -
Xiao HongPing,
Morsali Ali
Publication year - 2005
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.200590192
Subject(s) - chemistry , phenanthroline , crystallography , coordination number , coordination polymer , crystal structure , single crystal , coordination complex , ion , tris , elemental analysis , inorganic chemistry , metal , organic chemistry , biochemistry
A novel 3D polymeric Pb II complex involving three different hemidirected Pb II coordination spheres, [Pb 3 (phen) 3 (H 2 O) 2 (sip) 2 ] n ⋅3 H 2 O (phen=1,10‐phenanthroline and sip=5‐sulfoisophthalate=5‐sulfobenzene‐1,3‐dicarboxylate), was synthesized and characterized by elemental analysis and IR spectroscopy. Its single‐crystal X‐ray structure shows three types of Pb 2+ ions with coordination number six for Pb(1) and seven for Pb(2) and Pb(3). Two of the lead atoms, Pb(1) and Pb(3), are involved in PbPb interactions.