A Novel One‐Dimensional Coordination Polymer Involving Weak HgHg Interactions | Zendy

Morsali Ali | Zendy; Kempe Rhett | Zendy

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A Novel One‐Dimensional Coordination Polymer Involving Weak HgHg Interactions

Author(s) -

Morsali Ali,

Kempe Rhett

Publication year - 2005

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.200590160

Subject(s) - chemistry , pyridine , coordination polymer , atom (system on chip) , coordination sphere , crystallography , polymer , crystal structure , stereochemistry , medicinal chemistry , organic chemistry , computer science , embedded system

The novel, stable, one‐dimensional coordination polymer [Hg 3 (dmap) 6 ( μ ‐OAc) 2 ] n {(ClO 4 ) 4 } n ( 1 ; dmap = 4‐(dimethylamino)pyridine) has been synthesized and characterized. Single‐crystal X‐ray analysis showed that the coordination sphere of the two pertinent, zig‐zag‐oriented Hg II ‐atoms is different. One type of Hg‐atom in the N 2 O 4 HgHgN 2 O 4 environment is seven‐coordinate, with a weak HgHg interaction. The other type of Hg II ‐atom in the trans ‐HgN 2 O 4 units is six‐coordinate.

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