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Reactions of α , β ‐Enones with Diazo Compounds. Part 4
Author(s) -
Anaç Olcay,
Güngör Füsun Seyma,
Kahveci Çiĝdem,
Cansever M. Şerif
Publication year - 2004
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.200490039
Subject(s) - chemistry , substituent , diazo , medicinal chemistry , copper , atom (system on chip) , stereochemistry , organic chemistry , computer science , embedded system
In this study, ( E )‐ and ( Z )‐enones carrying only a phenyl substituent at their C( β ) atom were treaced with dimethyl diazomalonate in the presence of (acetylacetonato)copper(II). According to the configuration of the starting enones, the products were dioxole or dihydrofuran derivatives, significant heterocycles in natural products.