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Effect of the Media on the Quantum Yield of Singlet Oxygen (O 2 ( 1 Δ g )) Production by 9 H ‐Fluoren‐9‐one: Microheterogeneous Systems
Author(s) -
Martínez Claudia G.,
Braun André M.,
Oliveros Esther
Publication year - 2004
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.200490036
Subject(s) - chemistry , singlet oxygen , quantum yield , micelle , cyclohexane , solvent , microemulsion , yield (engineering) , singlet state , solvation , pulmonary surfactant , photochemistry , cationic polymerization , micellar solutions , inorganic chemistry , oxygen , aqueous solution , organic chemistry , excited state , biochemistry , physics , materials science , quantum mechanics , nuclear physics , metallurgy , fluorescence
The quantum yield ( Φ Δ ) of singlet oxygen (O 2 ( 1 Δ g ) production by 9 H ‐fluoren‐9‐one (FLU) is very sensitive to the nature of the solvent (0.02 in a highly polar and protic solvent, such as MeOH, to 1.0 in apolar solvents). This high sensitivity has been used for probing the interaction of FLU with micellar media and microemulsions based on anionic (sodium dodecyl sulfate, SDS; bis‐(2‐ethylhexyl)sodium sulfosuccinate, AOT), cationic (cetyltrimethylammonium chloride, CTAC) and nonionic ( Triton X‐100 , TX) surfactants. Values of Φ Δ of FLU vary in a wide range (0.05–1.0) in both microheterogeneous media and neat solvent, and provide information on the microenvironment of FLU, i.e. , on its localization within organized media. In ionic and nonionic micellar media, as well as in four‐component microemulsions, FLU is, to various extents, exposed to solvation by the polar and protic components of the microheterogeneous systems (water and/or butan‐1‐ol) in the micellar interfacial region ( Φ Δ =0.05–0.30). In contrast, in AOT reverse micelles (consisting of AOT as surfactant, cyclohexane as hydrophobic component, and water), FLU is located in the hydrophobic continuous pseudophase, and is totally separated from the micellar water pools ( Φ Δ ≈1.0).