Enantioselectivity in Odor Perception: Synthesis and Olfactory Properties of Iso‐ β ‐Bisabolol, a New Natural Product | Zendy

Braun Norbert A. | Zendy; Meier Manfred | Zendy; Schmaus Gerhard | Zendy; Hölscher Bernd | Zendy; Pickenhagen Wilhelm | Zendy

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Enantioselectivity in Odor Perception: Synthesis and Olfactory Properties of Iso‐ β ‐Bisabolol, a New Natural Product

Author(s) -

Braun Norbert A.,

Meier Manfred,

Schmaus Gerhard,

Hölscher Bernd,

Pickenhagen Wilhelm

Publication year - 2003

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.200390219

Subject(s) - chemistry , odor , natural product , sandalwood , natural (archaeology) , stereochemistry , organic chemistry , traditional medicine , geography , archaeology , medicine

The odorous trace constituent iso‐ β ‐bisabolol ( 4 ) was isolated from East Indian and Western Australian sandalwood oil and synthesized by using the ( E / Z )‐triene 12 (iso‐ γ ‐bisabolene) as a key intermediate. Only one of four stereoisomeric forms of 4 , (6 R ,7 R )‐ 4a , is odor active, having a strong floral, muguet ‐like, very pleasant scent.

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