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Synthesis and Structure Elucidation of a New Potent Sandalwood‐Oil Substitute
Author(s) -
Bajgrowicz Jerzy A.,
Frank Iris,
Fráter Georg,
Hennig Michael
Publication year - 1998
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19980810545
Subject(s) - sandalwood , chemistry , cyclopropane , stereochemistry , methanol , organic chemistry , ring (chemistry) , traditional medicine , medicine
New derivatives of campholenaldehyde (= 2‐(2,2,3‐trimethylcyclopent‐3‐enyl)ethanal bearing two cyclopropane moieties were synthesized, and the structure of the stereoisomer responsible for its exceptionally strong, diffusive, and natural sandalwood‐oil scent, ((1 S ,2 S )‐1‐methyl‐2‐{[1 S ,3 R ,5 R )‐1,2,2‐trimethylbicyclo[3.1.0]hex‐3‐yl]methyl}cyclopropyl)methanol ( 13a ), was elucidated.
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