Synthesis and Odor of Chiral Partial Structures of Khusimone. Part 1 | Zendy

Sprdizer Helmut | Zendy; Pichler Andrea | Zendy; Holzer Wolfgang | Zendy; Toth Irene | Zendy; Zuchart Bettina | Zendy

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Synthesis and Odor of Chiral Partial Structures of Khusimone. Part 1

Author(s) -

Sprdizer Helmut,

Pichler Andrea,

Holzer Wolfgang,

Toth Irene,

Zuchart Bettina

Publication year - 1997

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19970800114

Subject(s) - chemistry , odor , cyclopentene , conjugate , stereoselectivity , bicyclic molecule , stereochemistry , organic chemistry , catalysis , mathematical analysis , mathematics

Khusimone (1), one of the main odor‐donating compounds of vetiver oil is subject of the following study on structure/odor relationship. The omittance of the ethano bridge of the tricyclic khusimone leads to a bicyclic system. The stereoselective approach to this degraded structure is described, and the olfactory properties are studied. The key step of the synthesis of the hydrindane nucleus is based on a highly diastereoselective conjugate addition to a chiral oxo‐cyclopentene‐2‐carboxylate.

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