Premium
The Protonation of [Pt 3 (m̈‐CO) 3 (PCy 3 ) 3 ]
Author(s) -
Dahmen KlausHermann,
Imhof Daniel,
Venanzi Luigi M.
Publication year - 1994
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19940770415
Subject(s) - chemistry , protonation , cluster (spacecraft) , nuclear magnetic resonance spectroscopy , spectroscopy , medicinal chemistry , stereochemistry , crystallography , ion , organic chemistry , physics , computer science , programming language , quantum mechanics
The cluster [Pt 3 (m̈‐CO) 3 (PCy 3 ) 3 ] can be protonated with HBF 4 · OEt 2 to form the cluster [Pt 3 (m̈‐CO) 3 (PCy 3 ) 3 ](m̈ 3 ‐H) + BF 4 −( 2 ). This unstable compound was isolated and characterised by NMR and IR spectroscopy.