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3‐(Acylamino)‐3‐amino‐2‐nitroacrylonitriles from N ‐Acyl‐ S ‐methyl‐3,3‐diamino‐2‐nitroacrylthioimidates
Author(s) -
Trimiño María I. García,
Linden Anthony,
Heimgartner Heinz,
Cabrera Arturo Macías
Publication year - 1993
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19930760808
Subject(s) - chemistry , stereochemistry , medicinal chemistry
Reaction of N ‐acyl‐3,3‐diamino‐2‐nitroacrylthioamides 1 with MeI at room temperature leads to N ‐acyl‐ S ‐methyl‐3,3‐diamino‐2‐nitroacrylthioimidates 2 in moderate yields. The latter react with Hg(OAc) 2 in DMF yielding 3‐(acylamino)‐3‐amino‐2‐nitroacrylonitriles 8 . The structures of 2a and 8a were established by X‐ray crystallography.