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Über Diels‐Alder ‐Reaktionen des C 60 ‐Fullerens Vorläufige Mitteilung
Author(s) -
Krätler Bernhard,
Puchberger Michael
Publication year - 1993
Publication title -
helvetica chimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.74
H-Index - 82
eISSN - 1522-2675
pISSN - 0018-019X
DOI - 10.1002/hlca.19930760419
Subject(s) - chemistry , diels–alder reaction , medicinal chemistry , stereochemistry , organic chemistry , catalysis
On Diels‐Alder Reactions of the C 60 ‐Fullerene We report on the regioselective [4+2] cycloaddition of Buckminsterfullerene C 60 ( 1 ) at room temperature with 2,3‐dimethylbuta‐1,3‐diene and with the monoterpene 7‐methyl‐3‐methylideneocta‐1,6‐diene (= myrcene) and on the spectroscopic characterization of the corresponding crystalling monoadducts 2 and 3 . According to these experiments, 1 acts as a reactive dienophile, which can be functionalized regioselectively under mild and controlled conditons.