The Conformation of Medium‐Sized Organosilicon Heterocycles: First evidence for the existence of a boat‐boat conformation in a 12 H ‐dibenzo[ d,g ][1,3,2]dioxasilocin | Zendy

Fuhrer Hermann | Zendy; Meier Hansrudolf | Zendy; Rist Günther | Zendy; Pastor Stephen D. | Zendy; Shum Sai P. | Zendy; Clarke Frank H. | Zendy

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The Conformation of Medium‐Sized Organosilicon Heterocycles: First evidence for the existence of a boat‐boat conformation in a 12 H ‐dibenzo[ d,g ][1,3,2]dioxasilocin

Author(s) -

Fuhrer Hermann,

Meier Hansrudolf,

Rist Günther,

Pastor Stephen D.,

Shum Sai P.,

Clarke Frank H.

Publication year - 1993

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19930760408

Subject(s) - organosilicon , chemistry , cyclohexane conformation , solid state , crystal structure , crystallography , stereochemistry , molecule , polymer chemistry , organic chemistry , hydrogen bond

X‐Ray Crystal‐structure analysis of 2,4,8,10‐tetrakis(1,1‐dimethylethyl)‐6,6‐dimethyl‐12 H ‐dibenzo[ d,g ][1,3,2]‐dioxasilocin showed that its eight‐membered organosilicon heterocycle adopts a boat‐boat ( BB ) conformation in the solid state ( Figs. 2 and 3 ).

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