The  2 H, 2 H‐INADEQUATE experiment: Detection of One‐ and Two‐Spin Double Quantum Coherences | Zendy

Mons HansEgbert | Zendy; Bergander Klaus | Zendy; Günther Harald | Zendy

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The 2 H, 2 H‐INADEQUATE experiment: Detection of One‐ and Two‐Spin Double Quantum Coherences

Author(s) -

Mons HansEgbert,

Bergander Klaus,

Günther Harald

Publication year - 1993

Publication title -

helvetica chimica acta

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.74

H-Index - 82

eISSN - 1522-2675

pISSN - 0018-019X

DOI - 10.1002/hlca.19930760308

Subject(s) - chemistry , spin (aerodynamics) , deuterium , pyridine , atomic physics , quantum , quantum number , nuclear magnetic resonance , physics , quantum mechanics , thermodynamics , medicinal chemistry

The INADEQUATE experiment for spin‐1 nuclei has been extended to deuteron spin systems of the AX , AA ′ XX ′, and AA ′ MM ′ X type. Measurements with (3,3‐D 2 )norcampher, 4‐chloro(2,3,5,6‐D 4 )pyridine, and (D 5 )pyridine revealed correlation peaks due to two‐spin double quantum coherences and additional one‐spin double quantum peaks with coordinates F 1 = 2 ω i , F 2 =(ω i i = A, X) which were not observed in the 6 Li, 6 Li,‐INADEQUATE experiment described earlier.

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